Mechanistic details of the MnO+ + H2/D2 reaction through temperature-dependent kinetics and statistical modeling
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چکیده
منابع مشابه
Activation of methane by FeO+: determining reaction pathways through temperature-dependent kinetics and statistical modeling.
The temperature dependences of the rate constants and product branching ratios for the reactions of FeO(+) with CH4 and CD4 have been measured from 123 to 700 K. The 300 K rate constants are 9.5 × 10(-11) and 5.1 × 10(-11) cm(3) s(-1) for the CH4 and CD4 reactions, respectively. At low temperatures, the Fe(+) + CH3OH/CD3OD product channel dominates, while at higher temperatures, FeOH(+)/FeOD(+)...
متن کاملFurther insight into the reaction FeO(+) + H2 → Fe(+) + H2O: temperature dependent kinetics, isotope effects, and statistical modeling.
The reactions of FeO(+) with H2, D2, and HD were studied in detail from 170 to 670 K by employing a variable temperature selected ion flow tube apparatus. High level electronic structure calculations were performed and compared to previous theoretical treatments. Statistical modeling of the temperature and isotope dependent rate constants was found to reproduce all data, suggesting the reaction...
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In this investigation a non-equilibrium thermodynamic model of the temperature dependent biological growth of a living systems has been analyzed. The results are derived on the basis of Gompertzian growth equation. In this model, we have considered the temperature dependent growth rate and development parameter. The non-equilibrium thermodynamic model is also considered for exploring the variat...
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چکیده ندارد.
15 صفحه اولSynthesis of Polybutadiene Nanoparticles via Emulsion Polymerization: Effect of Reaction Temperature on the Polymer Microstructure, Particle Size and Reaction Kinetics
Polybutadiene nanoparticles were synthesized via batch emulsion polymerization of butadiene in the presence of potassium persulfate, disproportionate rosinate potassium cation and t-dodecyl mercaptane as initiator, emulsifier and chain transfer agent, respectively. Polymerization reaction was performed at different temperatures (60, 70 and 80 °C). Conversion was measured at the various time int...
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ژورنال
عنوان ژورنال: International Journal of Mass Spectrometry
سال: 2019
ISSN: 1387-3806
DOI: 10.1016/j.ijms.2018.10.011